The interaction between solid matter and positron (the antiparticle of electron) has provided important insights across a variety of disciplines, including atomic physics, materials science, elementary particle physics, and medicine. However, the experimental generation of positronic compounds by bombardment of positrons onto surfaces has proved challenging. In a new study, researchers detect molecular ion desorption from the surface of an ionic crystal when bombarded with positrons and propose a model based on positronic compound generation to explain their results.